"The two countries should carry on and further deepen their friendly relationship," Xu said.
This year marks the 55th anniversary of the establishment of bilateral diplomatic ties.
A series of events will celebrate the anniversary and the 2013 China-Cambodia Friendship Year.
Pan Guangxue, China's ambassador to Cambodia, said the two countries have formed a profound friendship through mutual support in the pursuit of national independence and prosperity.
"As an ambassador, I am deeply impressed by the two countries' mutual understanding, support, high-level mutual trust and people's friendship," he said in an article published in People's Daily.
China-Cambodia bilateral trade reached $2.92 billion in 2012. The countries have set a target of $5 billion by 2017.
By March, China's investment in Cambodia reached around $9.2 billion, accounting for 34 percent of all foreign investment in the country.
Premier Li Keqiang also met Peruvian President Ollanta Humala Tasso on Monday.
Life aboard a fishing boat under bridge in city of Chongqing